SYNTHESIS OF 9-R<sup>1</sup>-10-R-1,8-DIOXODECAHYDROACRIDINES AND DIOXIMES BASED ON THEM

Authors

  • Ю. М. Щекотихин Saratov State University, Saratov
  • Ю. А. Гетманенко Saratov State University, Saratov
  • Т. Г. Николаева Saratov State University, Saratov
  • А. П. Кривенько Saratov State University, Saratov

Keywords:

3-aminocyclohex-2-enone, 1,8-dioxodecahydroacridine dioxime, 1,8-dioxooctahydroacridinium chloride dioxime, condensation, oximation, methylenebis-3-aminocyclohex-2-enone

Abstract

3,3,6,6-Tetramethyl-9-R1-10-R-1,8-dioxo-1,2,3,4,5,6,7,8,9,10-decahydroacridines were synthesized through the intermediate α-R-methylenebisenamino ketones by the condensation of 5,5-dimethyl-3-N-R-aminocyclohex-2-enones with aliphatic, aromatic, and furan aldehydes (2-propanol, phosphorus pentoxide). It was found that the degree of substitution of the heterocycle in decahydroacridinediones has an effect on the direction of their transformations during oximation.

How to Cite
Shchekotikhin, Yu. M.; Getmanenko, Yu. A.; Nikolaeva, T. G.; Kriven'ko, A. P. Chem. Heterocycl. Compd. 2001, 37, 1228. [Khim. Geterotsikl. Soedin. 2001, 1344.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1013845426393

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Published

2001-10-25

Issue

No. 10 (2001)

Section

Original Papers